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bevorzugt sind schutzgruppen, insbe sondere ether oder carbonate, die sich unter milden, sauren oder neutralen bedingungen oder hydrogenolytisch abspalten lassen, wie tert-butyl-, benzyl-, 4-methoxybenzyl-, benz hydryl-, methoxymethyl-, 1-ethoxyethyl oder tetrahydro pyranylether, silylether wie trimethylsilyl- oder tert.- butyl-dimethylsilyl oder carbonate wie benzyloxycarbonyl- und tert.-butoxycarbonylderivate, die aus der peptid- und steroidchemie wohlbekannt sind.
preferred protective groups are those, especially ethers or carbonates, which can be eliminated under mild acidic or neutral conditions or by hydrogenolysis, such as tert-butyl, benzyl, 4-methoxybenzyl, benzhydryl, methoxymethyl, 1-ethoxyethyl or tetrahydropyranyl ethers, silyl ethers such as trimethylsilyl or tert.-butyldimethylsilyl or carbonates such as benzyloxycarbonyl and tert.-butoxycarbonyl derivatives, which are well known from peptide and steroid chemistry.
Last Update: 2014-12-03
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