Results for triéthylsulfonium translation from French to English

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triéthylsulfonium

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French

mots clés : liquides ioniques, triéthylsulfonium, haloaluminates, halohydrogénates, molarités, rmn, voltampérométrie, hydrure.

English

key words: ionic liquids, triethylsulfonium, haloaluminates, halohydrogenates, molarities, nmr, voltammetry, hydride.

Last Update: 2015-05-14
Usage Frequency: 1
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French

sels de triéthylsulfonium de la n-phosphonométhylglycine, leur production, leur utilisation comme régulateurs de croissance des plantes et herbicides et compositions les contenant.

English

triethylsulfonium salts of n-phosphonomethylglycine, production thereof, their use as plant growth regulators, herbicides and compositions containing them.

Last Update: 2014-11-25
Usage Frequency: 3
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French

la détermination de la structure cristalline des tetraphénylborates des cations suivants: triméthylsulfonium (me3s+,p21/n), triéthylsulfonium (et3s+, cmcm), triméthylsulfoxonium (me3 so+, p21/m), diphényliodonium (ph2i+, pnma) et 1-azoniapropellane (c10h18n+, p21/n), montre qu'en présence de régions à forte densité électronique locale (doublet électronique libre) dans le cation, ce dernier s'oriente de façon à minimiser la répulsion entre le doublet libre et les groupes phényles de l'anion les plus rapprochés, i.e. l'orientation du cation répond à l'interaction doublet libre avec le système π aromatique.

English

determination of the crystal structures of the tetraphenylborates of the trimethylsulfonium (me3s+,p21/n), triethylsulfonium (et3s+,cmcm), trimethylsulfoxonium (me3so+,p21/m), diphenyliodonium (ph2i+,pnma), and 1-azoniapropellane (c10h18n+,p21/n) cations has shown that when regions of high local electron density (lone electron pairs) are present in the cation, the cation orients itself so as to minimize the repulsion between the lone pair(s) and the nearest anion phenyl groups, i.e. the cation orientation responds to the lone pair – aromatic π system interaction.

Last Update: 2015-05-14
Usage Frequency: 1
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