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the simmons–smith reaction is generally subject to steric effects, and thus cyclopropanation usually takes place on the less hindered face.
a reação está geralmente sujeita a efeitos estéricos, e então ciclopropanação usualmente ocorre na face mais oculta.
Laatste Update: 2016-03-03
Gebruiksfrequentie: 1
Kwaliteit:
in this system, the standard diels-alder reaction a (4 + 2)cycloaddition, the 1,3-dipolar cycloaddition is a (3 + 2)cycloaddition and cyclopropanation of a carbene with an alkene a (2 + 1)cycloaddition.
isto faria a uma ] diels-alder, e a cicloadição 1,3-dipolar uma cicloadição (3 + 2).
Laatste Update: 2016-03-03
Gebruiksfrequentie: 1
Kwaliteit: