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barbu Știrbei was de zoon van prins alexandru Știrbey en maria ghika-comănești en kleinzoon van barbu Știrbei (1799-1869), de voorlaatste regerende vorst van walachije.
he was the son of prince alexandru Știrbey and his wife maria ghika-comănești, and grandson of another barbu dimitrie Știrbei (born bibescu, adopted Știrbei), who was prince of wallachia and died in 1869.