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suitable hydroboration reagents are, for example, diborane which is generally generated in situ by reaction of sodium borohydride with bf -etherate, diisoamylborane (bis[3-methylbut-2-yl]borane), 1,1,2-trimethylpropylborane, 9-borabicyclo[3.3.1]nonane, diisocamphenylborane, which are obtainable by hydroboration of the corresponding alkenes by means of diborane, chloroborane dimethyl sulfide, alkyldichloroboranes or h b—n(c h ) .
geeignete hydroborierungsreagenzien sind beispielsweise diboran, das in der regel in situ durch umsetzung von natriumborhydrid mit bf -etherat erzeugt wird, diisamylboran (bis-[3-methylbut-2-yl]boran), 1,1,2-trimethylpropylboran, 9-borbicyclo[3.3.1]nonan, diisocamphenylboran, die durch hydroborierung der entsprechenden alkene mit diboran erhältlich sind, chlorboran-dimethylsulfid, alkyldichlorborane oder h b-n(c h ) .
Última atualização: 2014-12-03
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