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on a aussi utilisé le tf-tms dans des réactions de rhamnosylation impliquant le tétra-o-acétyl α-l-rhamnopyrannose.
tms-tf was also used in rhamnosylation reactions with tetra-o-acetyl-α-l-rhamnopyranose.
Last Update: 2015-05-14
Usage Frequency: 1
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l'intermédiaire clé utilisé pour établir les liaisons α-rhamnopyrannosides-1,2 est le chlorure de o-acétyl-2 di-o-benzyl-3,4 α-l-rhamnopyrannosyle (1) qui est obtenu quantitativement à partir du di-o-benzyl-3,4 o-(méthoxyéthylidène)-1,2 β-l-rhamnopyrannose.
a key intermediate used to establish α-1,2-rhamnopyranoside linkages was 2-o-acetyl-3,4-di-o-benzyl-α-l-rhamnopyranosyl chloride (1), which was obtained in quantitative yield from 3,4-di-o-benzyl-1,2-o-(methoxyethylidene)-β-l-rhamnopyranose.
Last Update: 2015-05-14
Usage Frequency: 1
Quality: