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verfahren nach anspruch 1, bei dem der tertiäre phosphinligand neomenthyldiphenylphosphin ist.
a process according to claim 1 wherein said tertiary phosphine ligand is neomenthyldiphenylphosphine.
Last Update: 2014-12-05
Usage Frequency: 2
Quality:
verfahren nach anspruch 2, bei dem das kristallisierte neomenthyldiphenylphosphin eine reinheit von mindestens 97 mol.% hat, gemessen mittels 31 p-nmr.
a process according to claim 2 wherein the crystallized neomenthyldiphenylphosphine has a purity of at least 97 mole percent as measured by 31 p nmr.
Last Update: 2014-12-05
Usage Frequency: 4
Quality:
verfahren des anspruchs 52, wobei der organophosphorhaltige ligand ein phosphin ist, das aus der aus trimethylphosphin, triethylphosphin, tri-n-propylphosphin, triisopropylphosphin, tri-n-butylphosphin, tri-sec-butylphosphin, triisobutylphosphin, tri-t-butylphosphin, tricyclopentylphosphin, triallylphosphin, tricyclohexylphosphin, triphenylphosphin, trinaphthylphosphin, tri-p-tolylphosphin, tri-o-tolylphosphin, tri-m-tolylphosphin, tribenzylphosphin, tri(p-trifluormethylphenyl)phosphin, tris(trifluormethyl)phosphin, tri(p-fluorphenyl)phosphin, tri(p-trifluormethylphenyl)phosphin, allyldiphenylphosphin, benzyldiphenylphosphin, bis(2-furyl)phosphin, bis(4-methoxyphenyl)phenylphosphin, bis(4-methylphenyl)phosphin, bis(3,5-bis(trifluormethyl)phenyl)phosphin, t-butylbis(trimethylsilyl)phosphin, t-butyldiphenylphosphin, cyclohexyldiphenylphosphin, diallylphenylphosphin, dibenzylphosphin, dibutylphenylphosphin, dibutylphosphin, di-t-butylphosphin, dicyclohexylphosphin, diethylphenylphosphin, diisobutylphosphin, dimethylphenylphosphin, dimethyl(trimethylsilyl)phosphin, diphenylphosphin, diphenylpropylphosphin, diphenyl(p-tolyl)phosphin, diphenyl(trimethylsilyl)phosphin, diphenylvinylphosphin, divinylphenylphosphin, ethyldiphenylphosphin, (2-methoxyphenyl)methylphenylphosphin, tri-n-octylphosphin, tris(3,5-bis(trifluormethyl)phenyl)phosphin, tris(3-chlorphenyl)phosphin, tris(4-chlorphenyl)phosphin, tris(2,6-dimethoxyphenyl)phosphin, tris(3-fluorphenyl)phosphin, tris(2-furyl)phosphin, tris(2-methoxyphenyl)phosphin, tris(3-methoxyphenyl)phosphin, tris(4-methoxyphenyl)phosphin, tris(3-methoxypropyl)phosphin, tris(2-thienyl)phosphin, tris(2,4,6-trimethylphenyl)phosphin, tris(trimethylsilyl)phosphin, isopropyldiphenylphosphin, dicyclohexylphenylphosphin, (+)-neomenthyldiphenylphosphin, tribenzylphosphin, diphenyl(2-methoxyphenyl)phosphin, diphenyl(pentafluorphenyl)phosphin, bis(pentafluorphenyl)-phenylphosphin und tris(pentafluorphenyl)phosphin bestehenden gruppe ausgewählt ist.
the process of claim 52 wherein said organophosphorus containing ligand is a phosphine selected from the group consisting of trimethylphosphine, triethylphosphine, tri-n-propylphosphine, triisopropylphosphine, tri- n -butylphosphine, tri- sec -butylphosphine, tri- i -butylphosphine, tri- t -butylphosphine, tricyclopentylphosphine, triallylphosphine, tricyclohexylphosphine, triphenylphosphine, trinaphthylphosphine, tri- p -tolylphosphine, tri- o -tolylphosphine, tri- m -tolylphosphine, tribenzylphosphine, tri( p -trifluoromethylphenyl)phosphine, tris(trifluoromethyl)phosphine, tri( p -fluorophenyl)phosphine, tri( p -trifluoromethylphenyl)phosphine, allyldiphenylphosphine, benzyldiphenylphosphine, bis(2-furyl)phosphine, bis(4-methoxyphenyl)phenylphosphine, bis(4-methylphenyl)phosphine, bis(3,5-bis(trifluoromethyl)phenyl)phosphine, t -butylbis(trimethylsilyl)phosphine, t -butyldiphenylphosphine, cyclohexyldiphenylphosphine, diallylphenylphosphine, dibenzylphosphine, dibutylphenylphosphine, dibutylphosphine, di- t -butylphosphine, dicyclohexylphosphine, diethylphenylphosphine, di- i -butylphosphine, dimethylphenylphosphine, dimethyl(trimethylsilyl)phosphine, diphenylphosphine, diphenylpropylphosphine, diphenyl( p -tolyl)phosphine, diphenyl(trimethylsilyl)phosphine, diphenylvinylphosphine, divinylphenylphosphine, ethyldiphenylphosphine, (2-methoxyphenyl)methylphenylphosphine, tri-n-octylphosphine, tris(3,5-bis(trifluoromethyl)phenyl)phosphine, tris(3-chlorophenyl)phosphine, tris(4-chlorophenyl)phosphine, tris(2,6-dimethoxyphenyl)phosphine, tris(3-fluorophenyl)phosphine, tris(2-furyl)phosphine, tris(2-methoxyphenyl)phosphine, tris(3-methoxyphenyl)phosphine, tris(4-methoxyphenyl)phosphine, tris(3-methoxypropyl)phosphine, tris(2-thienyl)phosphine, tris(2,4,6-trimethylphenyl)phosphine, tris(trimethylsilyl)phosphine, isopropyldiphenylphosphine, dicyclohexylphenylphosphine, (+)-neomenthyldiphenylphosphine, tribenzylphosphine, diphenyl(2-methoxyphenyl)phosphine, diphenyl(pentafluorophenyl)phosphine, bis(pentafluorophenyl)phenylphosphine, and tris(pentafluorophenyl)phosphine.
Last Update: 2014-12-05
Usage Frequency: 2
Quality: